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Title: Thermal Decomposition of Methyl Nitrite: Kinetic Modeling of Detailed Product Measurements by Gas-Liquid Chromatography and Fourier Transform Infrared Spectroscopy
Journal: J. Phys. Chem.
Volume: 92
Page(s):
Year: 1988
Reference type: Journal article
Squib: 1988HE/SAN5474
Reaction:
CH3O· + HNO → CH3OH + NO
Reaction order:
2
Temperature:
450 - 520
K
Pressure: 1.33E-2 - 1.33 bar
Rate expression:
5.25x10-11 [cm3/molecule s]
Uncertainty:
2.51
Bath gas:
He
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
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