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Accessibility information
Author(s):   Heicklen, J.
Title:   The decomposition of alkyl nitrites and the reactions of alkoxyl radicals
Journal:   Adv. Photochem.
Volume:   14
Year:   1988
Reference type:   Journal article
Squib:   1988HEI177

Reaction:   (CH3)3CO· → (CH3)2CO + ·CH3
Reaction order:   1
Temperature:   298 - 450 K
Rate expression:   1.0x1015 [s-1] e-69010 [J/mole]/RT
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
298 8.01E2
300 9.65E2
325 8.11E3
350 5.02E4
375 2.44E5
400 9.74E5
425 3.30E6
450 9.77E6