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Accessibility information
Author(s):   Heicklen, J.
Title:   The decomposition of alkyl nitrites and the reactions of alkoxyl radicals
Journal:   Adv. Photochem.
Volume:   14
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988HEI177

Reaction:   C2H5C(CH3)2O(·) → (CH3)2CO + ·C2H5
Reaction order:   1
Temperature:   298 - 450 K
Rate expression:   1.0x1015 [s-1] e-64021 [J/mole]/RT
Category:  Review
Data type:   Extensive literature review

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
298 6.00E3
300 7.13E3
325 5.14E4
350 2.79E5
375 1.21E6
400 4.36E6
425 1.35E7
450 3.70E7