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Title: Analysis of the Chemically Activated CH2Cl/CH2Cl and CH3/CH2Cl Recombination Reactions at Elevated Temperatures Using the Bimolecular Quantum Rice-Ramsperger-Kassel (QRRK) Method
Journal: Ind. Eng. Chem. Res.
Volume: 27
Page(s): 447 - 451
Year: 1988
Reference type: Journal article
Squib: 1988KAR/SEN447-451
Reaction:
CH2ClCH2Cl → ·CH2Cl + ·CH2Cl
Reaction order:
1
Temperature:
500 - 1700
K
Rate expression:
8.68x1015 [s-1] e-364008 [J/mole]/RT
Category: Theory
Data type:
RRK(M) extrapolation
Pressure dependence:
Rate constant is high pressure limit
Comments:
Fall-off rate constants were presented in table at 0.67, 1.0, 3.0 and 10.0 atm for Ar and CH4 as bath gases.
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 500 | 8.16E-23 |
| 600 | 1.78E-16 |
| 700 | 5.98E-12 |
| 800 | 1.49E-8 |
| 900 | 6.49E-6 |
| 1000 | 8.42E-4 |
| 1100 | 4.50E-2 |
| 1200 | 1.24E0 |
| 1300 | 2.05E1 |
| 1400 | 2.28E2 |
| 1500 | 1.83E3 |
| 1600 | 1.14E4 |
| 1700 | 5.68E4 |