Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Kern, R.D.; Singh, H.J.; Wu, C.H.
Title:   Thermal decomposition of 1,2 butadiene
Journal:   Int. J. Chem. Kinet.
Volume:   20
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988KER/SIN731

Reaction:   1,3-ButadieneC2H3 + C2H3
Reaction order:   1
Temperature:   1300 - 2000 K
Pressure:  0.20 - 0.56 bar
Rate expression:   3.07x1012 [s-1] e-278535 [J/mole]/RT
Bath gas:   Ne
Category:  Experiment
Data type:   Derived from detailed balance/reverse rate

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1300 1.98E1
1350 5.13E1
1400 1.24E2
1450 2.84E2
1500 6.14E2
1550 1.26E3
1600 2.48E3
1650 4.67E3
1700 8.49E3
1750 1.49E4
1800 2.54E4
1850 4.20E4
1900 6.76E4
1950 1.06E5
2000 1.63E5