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Title: Pressure and temperature dependence of reactions proceeding via a bound complex. An approach for combustion and atmospheric chemistry modelers. Application to HO + CO → [HOCO] → H + CO2
Journal: Int. J. Chem. Kinet.
Volume: 20
Page(s):
Year: 1988
Reference type: Journal article
Squib: 1988LAR/STE27
Reaction:
CO + ·OH → CO2 + H·
Reaction order:
2
Temperature:
200 - 2200
K
Pressure: 1.33E-4 - 1.33 bar
Rate expression:
4.35x10-14 [cm3/molecule s] (T/298 K)1.35 e3035 [J/mole]/RT
Bath gas:
N2
Category: Experiment
Data type:
RRK(M) extrapolation
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 200 | 1.58E-13 |
| 300 | 1.48E-13 |
| 400 | 1.61E-13 |
| 500 | 1.82E-13 |
| 600 | 2.06E-13 |
| 700 | 2.32E-13 |
| 800 | 2.60E-13 |
| 900 | 2.90E-13 |
| 1000 | 3.21E-13 |
| 1100 | 3.53E-13 |
| 1200 | 3.87E-13 |
| 1300 | 4.21E-13 |
| 1400 | 4.56E-13 |
| 1500 | 4.92E-13 |
| 1600 | 5.28E-13 |
| 1700 | 5.66E-13 |
| 1800 | 6.04E-13 |
| 1900 | 6.43E-13 |
| 2000 | 6.82E-13 |
| 2100 | 7.23E-13 |
| 2200 | 7.63E-13 |