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Accessibility information
Author(s):   Muller-Markgraf, W.; Troe, J.
Title:   Thermal decomposition of ethylbenzene, styrene, and bromophenylethane: UV absorption study in shock waves
Journal:   J. Phys. Chem.
Volume:   92
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988MUL/TRO4914

Reaction:   EthylbenzeneBenzyl + ·CH3
Reaction order:   1
Temperature:   1250 - 1680 K
Pressure:  0.50 - 0.76 bar
Rate expression:   3.55x1015 [s-1] e-306804 [±3068 J/mole]/RT
Uncertainty:   1.3200001
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1250 5.37E2
1275 9.58E2
1300 1.67E3
1325 2.85E3
1350 4.78E3
1375 7.86E3
1400 1.27E4
1425 2.02E4
1450 3.15E4
1475 4.85E4
1500 7.36E4
1525 1.10E5
1550 1.63E5
1575 2.37E5
1600 3.42E5
1625 4.88E5
1650 6.88E5
1675 9.61E5
1680 1.03E6