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Accessibility information
Author(s):   Muller-Markgraf, W.; Troe, J.
Title:   Thermal decomposition of ethylbenzene, styrene, and bromophenylethane: UV absorption study in shock waves
Journal:   J. Phys. Chem.
Volume:   92
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988MUL/TRO4914

Reaction:   Ethylbenzene1-phenylethyl +
Reaction order:   1
Temperature:   1250 - 1680 K
Pressure:  0.50 - 0.76 bar
Rate expression:   2.51x1015 [s-1] e-340062 [J/mole]/RT
Rate constant is an upper limit.
Bath gas:   Ar
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1250 1.55E1
1275 2.94E1
1300 5.45E1
1325 9.86E1
1350 1.75E2
1375 3.03E2
1400 5.15E2
1425 8.60E2
1450 1.41E3
1475 2.28E3
1500 3.61E3
1525 5.65E3
1550 8.71E3
1575 1.32E4
1600 1.99E4
1625 2.94E4
1650 4.31E4
1675 6.24E4
1680 6.71E4