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Author(s):   Perrin, D.; Richard, C.; Martin, R.
Title:   H2S-promoted thermal isomerization of Cis-2-pentene to 1-pentene and trans-2-pentene around 800 K
Journal:   Int. J. Chem. Kinet.
Volume:   20
Year:   1988
Reference type:   Journal article
Squib:   1988PER/RIC621

Reaction:   1,3-Butadiene + ·CH3 → CH2CH=CHCH2CH3
Reaction order:   2
Temperature:   743 - 772 K
Pressure:  1.33E-2 - 0.13 bar
Rate expression:   1.05x10-13 [cm3/molecule s] e-31346 [J/mole]/RT
Bath gas:   2-(Z)-C5H10
Category:  Theory
Data type:   Estimated: thermochemical, kinetic, or other

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
743 6.56E-16
750 6.87E-16
772 7.93E-16