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Title: H2S-promoted thermal isomerization of Cis-2-pentene to 1-pentene and trans-2-pentene around 800 K
Journal: Int. J. Chem. Kinet.
Volume: 20
Page(s):
Year: 1988
Reference type: Journal article
Squib: 1988PER/RIC621
Reaction:
CH2CH=CHCH2CH3 → 1,3-Butadiene + ·CH3
Reaction order:
1
Reference reaction:
H2S + CH2CH=CHCH2CH3 → 2-(Z)-C5H10 + SH
Temperature:
743 - 772
K
Pressure: 1.33E-2 - 0.13 bar
Rate expression:
1.26x1013 [s-1] e-159638 [J/mole]/RT
Bath gas:
2-(Z)-C5H10
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 743 | 7.55E1 |
| 750 | 9.60E1 |
| 772 | 1.99E2 |