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Accessibility information
Author(s):   Rao, V.S.; Takeda, K.; Skinner, G.B.
Title:   Formation of H and D atoms in pyrolysis of 1,3-butadiene and 1,3 butadiene-1,1,4,4,-d4 behind shock waves
Journal:   Int. J. Chem. Kinet.
Volume:   20
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988RAO/TAK153

Reaction:   1,3-ButadieneC2H3 + C2H3
Reaction order:   1
Temperature:   1560 - 2210 K
Pressure:  2.73 bar
Rate expression:   1.8x1013 [s-1] e-355859 [J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1560 2.19E1
1600 4.34E1
1650 9.77E1
1700 2.10E2
1750 4.30E2
1800 8.49E2
1850 1.61E3
1900 2.97E3
1950 5.29E3
2000 9.15E3
2050 1.54E4
2100 2.53E4
2150 4.07E4
2200 6.40E4
2210 6.99E4