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Title: In Situ Radical Detection under very low pressure photolysis conditions using resonance-enhanced multiphoton ionization. Kinetics of CF3 radicals produced from IR multiphoton dissociation of hexafluoroacetone
Journal: J. Phys. Chem.
Volume: 92
Page(s): 5338 - 5347
Year: 1988
Reference type: Journal article
Squib: 1988ROB/GOL5338-5347
Reaction:
·CF3 + ·CF3 → C2F6
Reaction order:
2
Temperature:
298
K
Rate expression:
3.5x10-12 [cm3/molecule s]
Bath gas:
(CF3)2CO
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Mass spectrometry
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