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Author(s):   Robertson, R.M.; Golden, D.M.; Rossi, M.J.
Title:   In Situ Radical Detection under very low pressure photolysis conditions using resonance-enhanced multiphoton ionization. Kinetics of CF3 radicals produced from IR multiphoton dissociation of hexafluoroacetone
Journal:   J. Phys. Chem.
Volume:   92
Page(s):   5338 - 5347
Year:   1988
Reference type:   Journal article
Squib:   1988ROB/GOL5338-5347

Reaction:   ·CF3 + ·CF3C2F6
Reaction order:   2
Temperature:   298 K
Rate expression:   3.5x10-12 [cm3/molecule s]
Bath gas:   (CF3)2CO
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Mass spectrometry

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