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Title: The mechanism of thermal eliminations. Part 25. Arrhenius data for pyrolysis of isochroman-3-one, benzyl methyl ether, 2-hydroxyethylbenzene, phenyl acetate, and 3,4-dihydro-2H-pyran
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s):
Year: 1988
Reference type: Journal article
Squib: 1988TAY183
Reaction:
2-Phenylethanol → CH2O + Toluene
Reaction order:
1
Temperature:
720 - 767
K
Rate expression:
8.34x1012 [s-1] e-231974 [J/mole]/RT
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 720 | 1.24E-4 |
| 725 | 1.62E-4 |
| 750 | 5.83E-4 |
| 767 | 1.33E-3 |