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Author(s):   Tschuikow-Roux, E.; Faraji, F.; Paddison, S.; Niedzielski, J.; Miyokawa, K.
Title:   Kinetics of photochlorination of halogen (F, Cl, Br) substituted methanes
Journal:   J. Phys. Chem.
Volume:   92
Page(s):   1488 - 1495
Year:   1988
Reference type:   Journal article
Squib:   1988TSC/FAR1488-1495

Reaction:   CH3Br + ClHCl + ·CH2Br
Reaction order:   2
Reference reaction:   CH4 + Cl·CH3 + HCl
Temperature:   273 - 298 K
Pressure:  2.80E-2 bar
Rate expression:   3.16x10-11 [±6.31x10-12 cm3/molecule s] e-9977 [J/mole]/RT
Bath gas:   CH4
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
273 3.89E-13
275 4.02E-13
298 5.63E-13