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Accessibility information
Author(s):   Weissman, M.A.; Benson, S.W.
Title:   Rate parameters for the reactions of C2H3 and C4H5 with H2 and C2H2
Journal:   J. Phys. Chem.
Volume:   92
Page(s):  
Year:   1988
Reference type:   Journal article
Squib:   1988WEI/BEN4080

Reaction:   1,3-Butadiene + H2 + CH2=CHCH=CH·
Reaction order:   2
Temperature:   300 - 1500 K
Rate expression:   5.65x10-12 [cm3/molecule s] (T/298 K)0.70 e-25110 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 2.41E-16
400 3.65E-15
500 1.93E-14
600 6.01E-14
700 1.37E-13
800 2.59E-13
900 4.27E-13
1000 6.43E-13
1100 9.05E-13
1200 1.21E-12
1300 1.55E-12
1400 1.93E-12
1500 2.34E-12