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Accessibility information
Author(s):   Braun-Unkhoff, M.; Frank, P.; Just, Th.
Title:   A shock tube study on the thermal decomposition of toluene and of the phenyl radical at high temperatures
Journal:   Symp. Int. Combust. Proc.
Volume:   22
Page(s):   1053 - 1061
Year:   1989
Reference type:   Journal article
Squib:   1989BRA/FRA1053-1061

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1989BRA/FRA1053-1061   TolueneBenzyl +   1380 - 1700   3.60E15       3.74E05      1
  1989BRA/FRA1053-1061   Toluene·CH3 + Phenyl  1380 - 1700   <200              1
  1989BRA/FRA1053-1061   Toluene + H2 + Benzyl  1380 - 1700   8.30E-10       5.23E04      2
  1989BRA/FRA1053-1061   1,3-Butadiyne + → Products  1380 - 1700   1.66E-11              2
  1989BRA/FRA1053-1061   Benzyl → Other Products + 1,3-Cyclobutadiene  1380 - 1700   2.04E15       3.49E05      1
  1989BRA/FRA1053-1061   Benzyl → Bicyclo[2,2,1]-hepta-2,5-dien-7-yl  1380 - 1700   1.58E10       1.86E05      1
  1989BRA/FRA1053-1061   Phenyl → CH=CHCH=CHC≡CH  1450 - 1730   4.50E13       3.03E05      1
  1989BRA/FRA1053-1061   Phenyl + Benzene  1380 - 1700   1.32E-10              2
  1989BRA/FRA1053-1061   HCCCHCH· → 1,3-Butadiyne +   1380 - 1700   1.28E27   -13.90   2.57E05      1
  1989BRA/FRA1053-1061   CH2C≡CH + → Products  1380 - 1700   3.32E-11              2
  1989BRA/FRA1053-1061   Bicyclo[2,2,1]-hepta-2,5-dien-7-yl → C2H2 + Cyclopentadienyl  1380 - 1700   1.00E15       1.46E05      1
  1989BRA/FRA1053-1061   CH=CHCH=CHC≡CH → C2H2 + HCCCHCH·  1380 - 1700   1.69E26   -14.70   2.40E05      1
  1989BRA/FRA1053-1061   CH=CHCH=CHC≡CH → + (E)-HC≡CCH=CHC≡CH  1380 - 1700   1.80E24   -13.80   2.09E05      1

Search returned 13 records.