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Accessibility information
Author(s):   Braun-Unkhoff, M.; Frank, P.; Just, Th.
Title:   A shock tube study on the thermal decomposition of toluene and of the phenyl radical at high temperatures
Journal:   Symp. Int. Combust. Proc.
Volume:   22
Page(s):   1053 - 1061
Year:   1989
Reference type:   Journal article
Squib:   1989BRA/FRA1053-1061

Reaction:   TolueneBenzyl +
Reaction order:   1
Temperature:   1380 - 1700 K
Pressure:  1.49 - 6.07 bar
Rate expression:   3.6x1015 [s-1] e-374151 [±14966 J/mole]/RT
Bath gas:   Toluene
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1380 2.48E1
1400 3.95E1
1425 6.95E1
1450 1.20E2
1475 2.03E2
1500 3.37E2
1525 5.51E2
1550 8.87E2
1575 1.41E3
1600 2.20E3
1625 3.39E3
1650 5.15E3
1675 7.74E3
1700 1.15E4