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Title: Assessment of the cyano substituent effect in the inhibited pyrolysis kinetics of ω-bromonitriles in the gas phase
Journal: J. Phys. Chem.
Volume: 93
Page(s): 203 - 205
Year: 1989
Reference type: Journal article
Squib: 1989CHU/DOM203-205
Reaction:
BrCH2CH2C≡N → CH2CHCN + HBr
Reaction order:
1
Temperature:
703 - 743
K
Pressure: 5.13E-2 - 0.19 bar
Rate expression:
3.63x1013 [s-1] e-231974 [±6959 J/mole]/RT
Uncertainty:
2.75
Bath gas:
CH3CH=CH2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 703 | 2.11E-4 |
| 725 | 7.03E-4 |
| 743 | 1.79E-3 |