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Title: The UV absorption spectrum of the CCl3 radical and the kinetics of its mutual combination reaction from 253 to 623 K
Journal: Int. J. Chem. Kinet.
Volume: 21
Page(s): 715 - 727
Year: 1989
Reference type: Journal article
Squib: 1989DAN/CAR715-727
Reaction:
·CCl3 + Cl → CCl4
Reaction order:
2
Reference reaction:
CHCl3 + Cl → ·CCl3 + HCl
Temperature:
298
K
Pressure: 1.01 bar
Rate expression:
5.0x10-11 [cm3/molecule s]
Bath gas:
N2
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Vis-UV absorption
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