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Title: Reactions of vinyl and phenyl radicals with ethyne, ethene and benzene
Journal: Symp. Int. Combust. Proc.
Volume: 22
Page(s): 1023 - 1029
Year: 1989
Reference type: Journal article
Squib: 1989FAH/STE1023-1029
Reaction:
C2H4 + C2H3 → 1,3-Butadiene + H·
Reaction order:
2
Reference reaction:
C2H3 + C2H3 → 1,3-Butadiene
Temperature:
1000 - 1330
K
Rate expression:
1.05x10-12 [cm3/molecule s] e-12971 [J/mole]/RT
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 1000 | 2.20E-13 |
| 1025 | 2.29E-13 |
| 1050 | 2.37E-13 |
| 1075 | 2.45E-13 |
| 1100 | 2.54E-13 |
| 1125 | 2.62E-13 |
| 1150 | 2.70E-13 |
| 1175 | 2.78E-13 |
| 1200 | 2.86E-13 |
| 1225 | 2.93E-13 |
| 1250 | 3.01E-13 |
| 1275 | 3.08E-13 |
| 1300 | 3.16E-13 |
| 1325 | 3.23E-13 |
| 1330 | 3.24E-13 |