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Title: Reactions of o-xylene, m-xylene and p-xylene with atomic oxygen (O3P) in the gas phase
Journal: Z. Phys. Chem. (Neue Folge)
Volume: 165
Page(s): 9 - 22
Year: 1989
Reference type: Journal article
Squib: 1989FRE/SCH9-22
Reaction:
1,3-Dimethylbenzene + O· → Products
Reaction order:
2
Temperature:
298 - 868
K
Pressure: 2.00E-3 - 6.00E-3 bar
Rate expression:
3.82x10-11 [±8.47x10-12 cm3/molecule s] e-11308 [±1131 J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Mass spectrometry
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 298 | 3.98E-13 |
| 300 | 4.10E-13 |
| 350 | 7.84E-13 |
| 400 | 1.27E-12 |
| 450 | 1.86E-12 |
| 500 | 2.52E-12 |
| 550 | 3.22E-12 |
| 600 | 3.96E-12 |
| 650 | 4.71E-12 |
| 700 | 5.47E-12 |
| 750 | 6.23E-12 |
| 800 | 6.98E-12 |
| 850 | 7.71E-12 |
| 868 | 7.97E-12 |