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Accessibility information
Author(s):   Hess, W.P.; Tully, F.P.
Title:   Hydrogen-atom abstraction from methanol by OH
Journal:   J. Phys. Chem.
Volume:   93
Page(s):   1944 - 1947
Year:   1989
Reference type:   Journal article
Squib:   1989HES/TUL1944-1947

Reaction:   CH3OH + ·OH → Other Products + H2O
Reaction order:   2
Reference reaction:   CD3OH + ·OH → Products
Reference reaction order:   2
Temperature:   293 - 625 K
Pressure:  0.93 bar
Rate expression:   1.42 e1014 [±60.86 J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Laser induced fluorescence

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
293 2.15E0
300 2.13E0
325 2.07E0
350 2.01E0
375 1.97E0
400 1.93E0
425 1.89E0
450 1.86E0
475 1.84E0
500 1.81E0
525 1.79E0
550 1.77E0
575 1.76E0
600 1.74E0
625 1.73E0