Kinetics Database Resources
Rate Our Products and Services
Other Databases
NIST Standard Reference Data Program
NDRL-NIST Solution Kinetics Database
NIST Computational Chemistry Comparison and Benchmark Database
The NIST Reference on Constants, Units, and Uncertainty
Administrative Links
 |
Home ©NIST, 2013 Accessibility information |
Title: Measurement of absolute rate data for reactions of Rb(52S1/2), with CH3Cl, CH3Br, C2H5Br, CF3Cl, CF2Cl2, CFCl3, CF3Br and CF4 by time-resolved atomic resonance absorption spectroscopy
Journal: J. Photochem. Photobiol. A
Volume: 48
Page(s): 1 - 16
Year: 1989
Reference type: Journal article
Squib: 1989HUS/JI1-16
Reaction:
CF4 + Rb → ·CF3 + RbF
Reaction order:
2
Temperature:
744
K
Pressure: 2.67E-3 bar
Rate expression:
1.0x10-11 [±9.96x10-13 cm3/molecule s]
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Vis-UV absorption
View full bibliographic record.