Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Huybrechts, G.; Hubin, Y.; Van Mele, B.
Title:   Pyrolysis of 1,1,1-trichloroethane in the absence and the presence of added HCl and/or CCl4
Journal:   Int. J. Chem. Kinet.
Volume:   21
Page(s):   575 - 591
Year:   1989
Reference type:   Journal article
Squib:   1989HUY/HUB575-591

Reaction:   CH3CCl3CH2=CCl2 + HCl
Reaction order:   1
Temperature:   587 - 658 K
Pressure:  5.33E-2 - 0.20 bar
Rate expression:   7.08x1013 [s-1] e-226154 [J/mole]/RT
Uncertainty:   1.0700001
Bath gas:   CH3CCl3
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
587 5.32E-7
600 1.45E-6
625 8.90E-6
650 4.75E-5
658 7.90E-5