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Accessibility information
Author(s):   Lifshitz, A.; Bidani, M.; Suslensky, A.; Tamburu, C.
Title:   Pyrolysis of acrylonitrile at elevated temperatures. Studies with a single-pulse shock tube
Journal:   J. Phys. Chem.
Volume:   93
Page(s):   1369 - 1373
Year:   1989
Reference type:   Journal article
Squib:   1989LIF/BID1369-1373

Reaction:   CH2CHCNC2H2 + HCN
Reaction order:   1
Temperature:   1150 - 1430 K
Pressure:  3.24 bar
Rate expression:   1.78x1012 [s-1] e-284355 [±8564 J/mole]/RT
Uncertainty:   2.51
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1150 2.16E-1
1175 4.07E-1
1200 7.46E-1
1225 1.34E0
1250 2.33E0
1275 3.99E0
1300 6.69E0
1325 1.10E1
1350 1.77E1
1375 2.81E1
1400 4.38E1
1425 6.72E1
1430 7.31E1