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Author(s):   Nigenda, S.E.; McMillen, D.F.; Golden, D.M.
Title:   Thermal decomposition of dimethylnitramine and dimethylnitrosamine by pulsed laser pyrolysis
Journal:   J. Phys. Chem.
Volume:   93
Page(s):   1124 - 1130
Year:   1989
Reference type:   Journal article
Squib:   1989NIG/MCM1124-1130

Reaction:   (CH3)2C(OH)CH2C(O)CH3(CH3)2CO + (CH3)2CO
Reaction order:   1
Reference reaction:   tert-C4H9Briso-C4H8 + HBr
Temperature:   800 - 900 K
Pressure:  0.13 - 0.33 bar
Rate expression:   7.94x1011 [s-1] e-138020 [J/mole]/RT
Bath gas:   CO2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
800 7.73E2
825 1.45E3
850 2.62E3
875 4.58E3
900 7.75E3