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Author(s):   Szirovicza, L.; Woog, J.; Bardi, I.
Title:   Pyrolysis of pentanes in the presence of CCl4, II. Kinetics of the reaction C2H5 + CCl4 →’ C2H5Cl + CCl3
Journal:   Acta Chim. Acad. Sci. Hung.
Volume:   126
Page(s):   117 - 122
Year:   1989
Reference type:   Journal article
Squib:   1989SZI/WOO117-122

Reaction:   CCl4 + ·C2H5C2H5Cl + ·CCl3
Reaction order:   2
Reference reaction:   n-C5H12 + ·C2H5 → Other Products + C2H6
Temperature:   653 - 744 K
Pressure:  0.10 - 0.12 bar
Rate expression:   4.17x10-12 [cm3/molecule s] e-42570 [±5961 J/mole]/RT
Uncertainty:   5.0
Bath gas:   n-C5H12
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
653 1.64E-15
675 2.12E-15
700 2.78E-15
725 3.57E-15
744 4.28E-15