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Title: Rate constants for abstraction of hydrogen from benzene, toluene, and cyclopentane by methyl and ethyl radicals over the temperature range 650-770 K
Journal: Can. J. Chem.
Volume: 67
Page(s): 1541 - 1549
Year: 1989
Reference type: Journal article
Squib: 1989ZHA/AHO1541-1549
Reaction:
Cyclopentane + ·C2H5 → C2H6 + Cyclopentyl
Reaction order:
2
Reference reaction:
C2H4 + ·C2H5 → C2H6 + C2H3
Reference reaction order:
2
Temperature:
650 - 770
K
Pressure: 0.25 - 0.53 bar
Rate expression:
1.0 e22033 [±3958 J/mole]/RT
Uncertainty:
2.0
Bath gas:
C2H4
Category: Experiment
Data type:
Relative rate value measured
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [] |
|---|---|
| 650 | 5.90E1 |
| 675 | 5.07E1 |
| 700 | 4.41E1 |
| 725 | 3.87E1 |
| 750 | 3.42E1 |
| 770 | 3.12E1 |