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Accessibility information
Author(s):   Zhang, H.X.; Ahonkhai, S.I.; Back, M.H.
Title:   Rate constants for abstraction of hydrogen from benzene, toluene, and cyclopentane by methyl and ethyl radicals over the temperature range 650-770 K
Journal:   Can. J. Chem.
Volume:   67
Page(s):   1541 - 1549
Year:   1989
Reference type:   Journal article
Squib:   1989ZHA/AHO1541-1549

Reaction:   Toluene + ·CH3CH4 + Benzyl
Reaction order:   2
Reference reaction:   C2H4 + ·CH3CH4 + C2H3
Temperature:   650 - 770 K
Pressure:  0.29 - 0.48 bar
Rate expression:   4.17x10-14 [cm3/molecule s] e-29018 [±6959 J/mole]/RT
Uncertainty:   3.1600001
Bath gas:   C2H4
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
650 1.94E-16
675 2.37E-16
700 2.85E-16
725 3.38E-16
750 3.97E-16
770 4.48E-16