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Accessibility information
Author(s):   Baggott, J.E.; Blitz, M.A.; Frey, H.M.; Walsh, R.
Title:   Absolute rate constants for the gas-phase Si-H insertion reactions of dimethylsilylene with silane and the methylsilanes in the temperature range 300-600 K
Journal:   J. Am. Chem. Soc.
Volume:   112
Page(s):   8337 - 8343
Year:   1990
Reference type:   Journal article
Squib:   1990BAG/BLI8337-8343

Associated entries:

Search Results

Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

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Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1990BAG/BLI8337-8343   CH3SiH3 + (CH3)2Si → CH3SiH2SiH(CH3)2  295 - 608   1.26E-13       -6726   1.90E-12  2
  1990BAG/BLI8337-8343   (CH3)3SiH + (CH3)2Si → (CH3)3SiSiH(CH3)2  295 - 603   3.89E-14       -1.12E04   3.61E-12  2
  1990BAG/BLI8337-8343   (CH3)2SiH2 + (CH3)2Si → (CH3)2SiHSiH(CH3)2  295 - 596   7.09E-14       -1.06E04   5.03E-12  2
  1990BAG/BLI8337-8343   (CH3)2Si + SiH4 → H3SiSiH(CH3)2  295 - 602   2.87E-13       1247   1.74E-13  2
Search returned 4 records.