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Accessibility information
Author(s):   Bennett, P.J.; Kerr, J.A.
Title:   Kinetics of the reactions of hydroxyl radicals with aliphatic ethers studied under simulated atmospheric conditions: temperature dependences of the rate coefficients
Journal:   J. Atmos. Chem.
Volume:   10
Page(s):   29 - 38
Year:   1990
Reference type:   Journal article
Squib:   1990BEN/KER29-38

Reaction:   tert-C4H9OCH3 + ·OH → Other Products + H2O
Reaction order:   2
Reference reaction:   (C2H5)2O + ·OH → Other Products + H2O
Temperature:   242 - 328 K
Pressure:  1.01 bar
Rate expression:   4.0x10-12 [±1.33x10-12 cm3/molecule s] e-848 [±585 J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Derived from fitting to a complex mechanism
Excitation technique:   Direct photolysis
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
242 2.63E-12
250 2.66E-12
275 2.76E-12
300 2.85E-12
325 2.92E-12
328 2.93E-12