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Accessibility information
Author(s):   Brand, U.; Hippler, H.; Lindemann, L.; Troe, J.
Title:   C-C and C-H bond splits of laser-excited aromatic molecules. 1. Specific and thermally averaged rate constants
Journal:   J. Phys. Chem.
Volume:   94
Page(s):   6305 - 6316
Year:   1990
Reference type:   Journal article
Squib:   1990BRA/HIP6305-6316

Reaction:   1,2-Dimethylbenzene2-Methylbenzyl +
Reaction order:   1
Temperature:   1100 - 1900 K
Rate expression:   1.1x1016 [s-1] e-373320 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1100 2.06E-2
1150 1.22E-1
1200 6.19E-1
1250 2.76E0
1300 1.10E1
1350 3.95E1
1400 1.30E2
1450 3.92E2
1500 1.10E3
1550 2.89E3
1600 7.15E3
1650 1.67E4
1700 3.72E4
1750 7.92E4
1800 1.61E5
1850 3.17E5
1900 6.00E5