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Accessibility information
Author(s):   Brand, U.; Hippler, H.; Lindemann, L.; Troe, J.
Title:   C-C and C-H bond splits of laser-excited aromatic molecules. 1. Specific and thermally averaged rate constants
Journal:   J. Phys. Chem.
Volume:   94
Page(s):   6305 - 6316
Year:   1990
Reference type:   Journal article
Squib:   1990BRA/HIP6305-6316

Reaction:   3-Methylbenzyl + 1,3-Dimethylbenzene
Reaction order:   2
Temperature:   300 - 1900 K
Rate expression:   2.54x10-10 [cm3/molecule s] e-615 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   High or low pressure extrapolation
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
300 1.99E-10
400 2.11E-10
500 2.19E-10
600 2.25E-10
700 2.29E-10
800 2.32E-10
900 2.34E-10
1000 2.36E-10
1100 2.38E-10
1200 2.39E-10
1300 2.40E-10
1400 2.41E-10
1500 2.42E-10
1600 2.43E-10
1700 2.43E-10
1800 2.44E-10
1900 2.44E-10