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Accessibility information
Author(s):   Gill, M.T.; Taylor, R.
Title:   The mechanism of thermal eliminations. Part 27. Steric acceleration in pyrolysis of 3,3,3-tris(trimethylsilyl)propyl acetate
Journal:   J. Chem. Soc. Perkin Trans. 2
Page(s):   1715 - 1716
Year:   1990
Reference type:   Journal article
Squib:   1990GIL/TAY1715-1716

Reaction:   CH3COOC2H5CH3C(O)OH + C2H4
Reaction order:   1
Temperature:   648 - 697 K
Rate expression:   2.09x1012 [s-1] e-199547 [J/mole]/RT
Bath gas:   CH3COOC2H5
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   IR absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
648 1.72E-4
650 1.93E-4
675 7.56E-4
697 2.32E-3