Kinetics Database Logo

Kinetics Database Resources

Simple Reaction Search

Search Reaction Database

Search Bibliographic Database

Set Unit Preferences

Feedback

Rate Our Products and Services

Help


Other Databases

NIST Standard Reference Data Program

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...


Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

  NIST Logo Home
©NIST, 2013
Accessibility information
Author(s):   Hippler, H.; Reihs, C.; Troe, J.
Title:   Elementary steps in the pyrolysis of toluene and benzyl radicals
Journal:   Z. Phys. Chem. (Neue Folge)
Volume:   167
Page(s):   1 - 16
Year:   1990
Reference type:   Journal article
Squib:   1990HIP/REI1-16

Reaction:   Toluene → Products
Reaction order:   1
Temperature:   1200 - 1500 K
Pressure:  7.47E-2 - 4.96 bar
Rate expression:   1.0x1015 [s-1] e-360017 [±21618 J/mole]/RT
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1200 2.13E-1
1225 4.46E-1
1250 9.04E-1
1275 1.78E0
1300 3.42E0
1325 6.42E0
1350 1.18E1
1375 2.11E1
1400 3.70E1
1425 6.36E1
1450 1.07E2
1475 1.78E2
1500 2.91E2