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Title: Elementary steps in the pyrolysis of toluene and benzyl radicals
Journal: Z. Phys. Chem. (Neue Folge)
Volume: 167
Page(s): 1 - 16
Year: 1990
Reference type: Journal article
Squib: 1990HIP/REI1-16
Reaction:
Toluene + H· → H2 + Benzyl
Reaction order:
2
Temperature:
600 - 1800
K
Rate expression:
2.09x10-10 [cm3/molecule s] e-35004 [J/mole]/RT
Bath gas:
Ar
Category: Review
Data type:
Experimental value and limited review
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 600 | 1.88E-13 |
| 700 | 5.11E-13 |
| 800 | 1.08E-12 |
| 900 | 1.95E-12 |
| 1000 | 3.11E-12 |
| 1100 | 4.55E-12 |
| 1200 | 6.27E-12 |
| 1300 | 8.21E-12 |
| 1400 | 1.03E-11 |
| 1500 | 1.26E-11 |
| 1600 | 1.51E-11 |
| 1700 | 1.76E-11 |
| 1800 | 2.02E-11 |