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Title: Adduct formation of OH radicals with benzene, toluene, and phenol and consecutive reactions of the adducts with NOx and O2
Journal: Ber. Bunsenges. Phys. Chem.
Volume: 94
Page(s): 1375 - 1379
Year: 1990
Reference type: Journal article
Squib: 1990KNI/KOC1375-1379
Reaction:
Toluene + ·OH → Adduct
Reaction order:
2
Temperature:
299 - 340
K
Pressure: 0.13 bar
Rate expression:
2.19x10-13 [±8.97x10-14 cm3/molecule s] e8314 [±1081 J/mole]/RT
Bath gas:
Ar
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
Resonance fluorescence
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 299 | 6.21E-12 |
| 300 | 6.14E-12 |
| 325 | 4.75E-12 |
| 340 | 4.15E-12 |