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Accessibility information
Author(s):   Lightfoot, P.D.; Veyret, B.; Lesclaux, R.
Title:   Flash photolysis study of the CH3O2 + HO2 reaction between 248 and 573 K
Journal:   J. Phys. Chem.
Volume:   94
Page(s):   708 - 714
Year:   1990
Reference type:   Journal article
Squib:   1990LIG/VEY708-714

Reaction:   CH3OH + Cl(·)CH2OH + HCl
Reaction order:   2
Reference reaction:   CH4 + Cl·CH3 + HCl
Reference reaction order:   2
Temperature:   248 - 573 K
Pressure:  1.01 bar
Rate expression:   4.58 e11640 [J/mole]/RT
Bath gas:   N2
Category:  Experiment
Data type:   Relative rate value measured
Excitation technique:   Flash photolysis (laser or conventional)
Analytical technique:   Vis-UV absorption

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
248 1.30E3
250 1.24E3
275 7.44E2
300 4.87E2
325 3.40E2
350 2.50E2
375 1.92E2
400 1.52E2
425 1.23E2
450 1.03E2
475 8.73E1
500 7.53E1
525 6.59E1
550 5.84E1
573 5.27E1