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Accessibility information
Author(s):   Nelson, L.; Rattigan, O.; Neavyn, R.; Sidebottom, H.; Treacy, J.; Nielsen, O.J.
Title:   Absolute and relative rate constants for the reactions of hydroxyl radicals and chlorine atoms with a series of aliphatic alcohols and ethers at 298 K
Journal:   Int. J. Chem. Kinet.
Volume:   22
Page(s):   1111 - 1126
Year:   1990
Reference type:   Journal article
Squib:   1990NEL/RAT1111-1126

Associated entries:

Search Results


Rate expression:  k(T) = A (T/298 K)n e-Ea/RT
Rate expression units:
First order:  s-1
Second order:  cm3/molecule s
Third order:  cm6/molecule2 s
R = 8.314472 J / mole K
Energy Units J   Molecular Units Molecule
Pressure Units bar   Temperature Units K
Base Volume Unit cm   Reference Temperature 298.0
Evaluation Temperature 298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |
Plot   Squib   Reaction   Temp [K]   A   n   Ea [J/mole]   k(298.00 K)   Order
  1990NEL/RAT1111-1126   (C2H5)2O + ·OH → Other Products + H2O  298   1.13E-11           1.13E-11  2
  1990NEL/RAT1111-1126   (C2H5)2O + ·Cl → Other Products + HCl  298   2.54E-10           2.54E-10  2
  1990NEL/RAT1111-1126   C2H5OH + ·OH → Other Products + H2O  298   3.04E-12           3.04E-12  2
  1990NEL/RAT1111-1126   C2H5OH + ·Cl → Other Products + HCl  298   1.01E-10           1.01E-10  2
  1990NEL/RAT1111-1126   CH3OH + ·OH → Other Products + H2O  298   9.00E-13           9.00E-13  2
  1990NEL/RAT1111-1126   CH3OH + ·Cl(·)CH2OH + HCl  298   4.78E-11           4.78E-11  2
  1990NEL/RAT1111-1126   iso-C3H7OH + ·OH → Other Products + H2O  298   5.70E-12           5.70E-12  2
  1990NEL/RAT1111-1126   iso-C3H7OH + ·Cl → Other Products + HCl  298   8.40E-11           8.40E-11  2
  1990NEL/RAT1111-1126   n-C3H7OH + ·OH → Other Products + H2O  298   5.65E-12           5.65E-12  2
  1990NEL/RAT1111-1126   n-C3H7OH + ·Cl → Other Products + HCl  298   1.49E-10           1.49E-10  2
  1990NEL/RAT1111-1126   n-C4H9OH + ·OH → Other Products + H2O  298   7.80E-12           7.80E-12  2
  1990NEL/RAT1111-1126   n-C4H9OH + ·Cl → Other Products + HCl  298   2.04E-10           2.04E-10  2
  1990NEL/RAT1111-1126   n-C5H11OH + ·OH → Other Products + H2O  298   1.20E-11           1.20E-11  2
  1990NEL/RAT1111-1126   n-C5H11OH + ·Cl → Other Products + HCl  298   2.51E-10           2.51E-10  2
  1990NEL/RAT1111-1126   (iso-C3H7)2O + ·OH → Other Products + H2O  298   1.07E-11           1.07E-11  2
  1990NEL/RAT1111-1126   (iso-C3H7)2O + ·Cl → Other Products + HCl  298   1.51E-10           1.51E-10  2
  1990NEL/RAT1111-1126   n-C6H13OH + ·OH → Other Products + H2O  298   1.22E-11           1.22E-11  2
  1990NEL/RAT1111-1126   n-C6H13OH + ·Cl → Other Products + HCl  298   2.96E-10           2.96E-10  2
  1990NEL/RAT1111-1126   (n-C3H7)2O + ·OH → Other Products + H2O  298   1.99E-11           1.99E-11  2
  1990NEL/RAT1111-1126   (n-C3H7)2O + ·Cl → Other Products + HCl  298   3.62E-10           3.62E-10  2
  1990NEL/RAT1111-1126   n-C7H15OH + ·OH → Other Products + H2O  298   1.37E-11           1.37E-11  2
  1990NEL/RAT1111-1126   n-C7H15OH + ·Cl → Other Products + HCl  298   3.49E-10           3.49E-10  2
  1990NEL/RAT1111-1126   1-Octanol + ·OH → Other Products + H2O  298   1.44E-11           1.44E-11  2
  1990NEL/RAT1111-1126   1-Octanol + ·Cl → Other Products + HCl  298   3.94E-10           3.94E-10  2
  1990NEL/RAT1111-1126   (CH3)2O + ·OHH2O + CH3OCH2  298   2.36E-12           2.36E-12  2
  1990NEL/RAT1111-1126   (CH3)2O + ·ClHCl + CH3OCH2  298   1.51E-10           1.51E-10  2
  1990NEL/RAT1111-1126   (n-C4H9)2O + ·OH → Other Products + H2O  298   2.72E-11           2.72E-11  2
  1990NEL/RAT1111-1126   (n-C4H9)2O + ·Cl → Other Products + HCl  298   4.40E-10           4.40E-10  2
  1990NEL/RAT1111-1126   n-C4H9OC2H5 + ·OH → Other Products + H2O  298   1.88E-11           1.88E-11  2
  1990NEL/RAT1111-1126   (n-C5H11)2O + ·OH → Other Products + H2O  298   3.40E-11           3.40E-11  2
  1990NEL/RAT1111-1126   (n-C5H11)2O + ·Cl → Other Products + HCl  298   4.97E-10           4.97E-10  2

Search returned 31 records.