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Accessibility information
Author(s):   Saito, K.; Sasaki, T.; Yoshinobu, I.; Imamura, A.
Title:   Thermal decomposition of ethyl acetate. Branching ratio of the competing paths in the pyrolysis of the produced acetic acid
Journal:   Chem. Phys. Lett.
Volume:   170
Page(s):  
Year:   1990
Reference type:   Journal article
Squib:   1990SAI/SAS385

Reaction:   CH3COOC2H5CH3C(O)OH + C2H4
Reaction order:   1
Temperature:   1300 - 1800 K
Pressure:  8.00E-3 - 0.16 bar
Rate expression:   2.57x1017 [s-1] e-274378 [J/mole]/RT
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Gas chromatography

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1300 2.43E6
1350 6.22E6
1400 1.49E7
1450 3.36E7
1500 7.17E7
1550 1.46E8
1600 2.84E8
1650 5.30E8
1700 9.54E8
1750 1.66E9
1800 2.80E9