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Title: Kinetics of the thermolysis of [n.2.2]propellanes and related compounds. Mechanism of the thermolysis of bicyclo[2.2.0]hexanes
Journal: J. Am. Chem. Soc.
Volume: 112
Page(s): 5854 - 5861
Year: 1990
Reference type: Journal article
Squib: 1990WIB/CAR5854-5861
Reaction:
Cyclooctane,1,5-bis(methylene)- → Other Products + 1,2-Dimethylbenzene
Reaction order:
1
Temperature:
588 - 743
K
Rate expression:
1.0x1016 [s-1] e-251929 [±7558 J/mole]/RT
Bath gas:
He
Category: Experiment
Data type:
Derived from fitting to a complex mechanism
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [s-1] |
|---|---|
| 588 | 4.17E-7 |
| 600 | 1.17E-6 |
| 625 | 8.82E-6 |
| 650 | 5.69E-5 |
| 675 | 3.20E-4 |
| 700 | 1.59E-3 |
| 725 | 7.07E-3 |
| 743 | 1.95E-2 |