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Author(s):   Abbatt, J.P.D.; Anderson, J.G.
Title:   High-pressure discharge flow kinetics and frontier orbital mechanistic analysis for OH + CH2CCl2, cis-CHClCHCl, trans-CHClCHCl, CFClCF2 and CF2CCl2 →’ products
Journal:   J. Phys. Chem.
Volume:   95
Page(s):   2382 - 2390
Year:   1991
Reference type:   Journal article
Squib:   1991ABB/AND2382-2390

Reaction:   CH2=CCl2 + ·OH → Products
Reaction order:   2
Temperature:   297 - 368 K
Pressure:  3.47E-2 - 0.11 bar
Rate expression:   1.6x10-12 [cm3/molecule s] e4656 [±931 J/mole]/RT
Bath gas:   CH2=CCl2
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Electron beam
Analytical technique:   Vis-UV emission

View full bibliographic record.

Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [cm3/molecule s]
297 1.05E-11
300 1.04E-11
325 8.97E-12
350 7.93E-12
368 7.33E-12