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Title: High-pressure discharge flow kinetics and frontier orbital mechanistic analysis for OH + CH2CCl2, cis-CHClCHCl, trans-CHClCHCl, CFClCF2 and CF2CCl2 → products
Journal: J. Phys. Chem.
Volume: 95
Page(s): 2382 - 2390
Year: 1991
Reference type: Journal article
Squib: 1991ABB/AND2382-2390
Reaction:
CH2=CCl2 + ·OH → Products
Reaction order:
2
Temperature:
297 - 368
K
Pressure: 3.47E-2 - 0.11 bar
Rate expression:
1.6x10-12 [cm3/molecule s] e4656 [±931 J/mole]/RT
Bath gas:
CH2=CCl2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Electron beam
Analytical technique:
Vis-UV emission
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 297 | 1.05E-11 |
| 300 | 1.04E-11 |
| 325 | 8.97E-12 |
| 350 | 7.93E-12 |
| 368 | 7.33E-12 |