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Author(s):   Bogdan, P.L.; Wells, J.R.; Weitz, E.
Title:   Bond dissociation energies and kinetics for the reaction of W(CO)5 with the unlikely ligands N2O and CF2Cl2
Journal:   J. Am. Chem. Soc.
Volume:   113
Page(s):   1294 - 1299
Year:   1991
Reference type:   Journal article
Squib:   1991BOG/WEL1294-1299

Reaction:   CF2Cl2 + W(CO)5 → Adduct
Reaction order:   2
Temperature:   298 K
Pressure:  1.33E-2 bar
Rate expression:   1.2x10-10 [±1.99x10-11 cm3/molecule s]
Bath gas:   Ar
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Direct photolysis
Analytical technique:   Fourier transform (FTIR)

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