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Title: Bond dissociation energies and kinetics for the reaction of W(CO)5 with the unlikely ligands N2O and CF2Cl2
Journal: J. Am. Chem. Soc.
Volume: 113
Page(s): 1294 - 1299
Year: 1991
Reference type: Journal article
Squib: 1991BOG/WEL1294-1299
Reaction:
CF2Cl2 + W(CO)5 → Adduct
Reaction order:
2
Temperature:
298
K
Pressure: 1.33E-2 bar
Rate expression:
1.2x10-10 [±1.99x10-11 cm3/molecule s]
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Direct photolysis
Analytical technique:
Fourier transform (FTIR)
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