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Title: Silicon-containing heterocycles. 59. Effects of substituents at silicon on the retrodiene decomposition of silacyclopentenes in the gas phase
Journal: J. Gen. Chem. USSR
Volume: 61
Page(s): 143 - 146
Year: 1991
Reference type: Journal article
Squib: 1991CHE/BYK143-146
Reaction:
Silacyclopent-3-ene, 1,1-difluoro- → 1,3-Butadiene + SiF2
Reaction order:
1
Temperature:
823
K
Rate expression:
1.37x10-2 [s-1]
Bath gas:
He
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
Gas chromatography
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