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Accessibility information
Author(s):   Cohen, N.; Westberg, K.R.
Title:   Chemical kinetic data sheets for high-temperature reactions. Part II
Journal:   J. Phys. Chem. Ref. Data
Volume:   20
Page(s):   1211 - 1311
Year:   1991
Reference type:   Journal article
Squib:   1991COH/WES1211-1311

Reaction:   n-C4H10 + sec-C4H9 + ·OH
Reaction order:   2
Reference reaction:   n-C4H10 + n-C4H9 + ·OH
Reference reaction order:   2
Temperature:   298 - 2000 K
Rate expression:   2.72x10-1(T/298 K)0.20 e12222 [J/mole]/RT
Uncertainty:   3.1600001
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 3.77E1
300 3.66E1
400 1.14E1
500 5.71E0
600 3.63E0
700 2.63E0
800 2.08E0
900 1.74E0
1000 1.51E0
1100 1.34E0
1200 1.22E0
1300 1.13E0
1400 1.06E0
1500 1.00E0
1600 9.54E-1
1700 9.15E-1
1800 8.82E-1
1900 8.54E-1
2000 8.30E-1