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Title: Formation of glyoxyloxyl chloride, HC(O)C(O)Cl, in the gas-phase oxidation of trichloroethene by NO2
Journal: J. Chem. Soc. Perkin Trans. 2
Page(s): 1459 - 1462
Year: 1991
Reference type: Journal article
Squib: 1991CZA1459-1462
Reaction:
C2HCl3 + NO2 → Products
Reaction order:
2
Temperature:
343 - 362
K
Pressure: 2.51E-2 - 0.27 bar
Rate expression:
1.01x10-18 [cm3/molecule s] e-38080 [J/mole]/RT
Bath gas:
NO2
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Thermal
Analytical technique:
IR absorption
View full bibliographic record.
Rate constant values calculated from the Arrhenius expression:
| T (K) | k(T) [cm3/molecule s] |
|---|---|
| 343 | 1.61E-24 |
| 350 | 2.10E-24 |
| 362 | 3.25E-24 |