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Accessibility information
Author(s):   Glauser, W.A.; Koszykowski, M.L.
Title:   Anomalous methoxy radical yields in the fluorine + methanol reaction. 2. Theory
Journal:   J. Phys. Chem.
Volume:   95
Page(s):   10705 - 10713
Year:   1991
Reference type:   Journal article
Squib:   1991GLA/KOS10705-10713

Reaction:   CH3OH + ·FCH3 + HF
Reaction order:   2
Reference reaction:   CH3OH + ·F → Other Products + HF
Reference reaction order:   2
Temperature:   298 - 960 K
Rate expression:   7.91x10-1(T/298 K)-0.22 e-283 [J/mole]/RT
Category:  Theory
Data type:   Transition state theory

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) []
298 7.06E-1
300 7.05E-1
350 6.93E-1
400 6.81E-1
450 6.70E-1
500 6.59E-1
550 6.50E-1
600 6.41E-1
650 6.32E-1
700 6.24E-1
750 6.17E-1
800 6.10E-1
850 6.03E-1
900 5.97E-1
950 5.91E-1
960 5.90E-1