Kinetics Database Resources

Other Databases

NIST Chemistry Web Book

NDRL-NIST Solution Kinetics Database

NIST Computational Chemistry Comparison and Benchmark Database

The NIST Reference on Constants, Units, and Uncertainty

More...

Administrative Links

NIST home page

MML home page

Chemical and Biochemical Reference Data Division

MML home page

Chemical and Biochemical Reference Data Division

Home
©NIST, 2013
Accessibility information

Author(s):   Ryther, R.J.; Weitz, E.
Title:   Reaction kinetics of coordinatively unsaturated iron carbonyls formed on gas-phase excimer laser photolysis of Fe(CO)₅
Journal:   J. Phys. Chem.
Volume:   95
Page(s):   9841 - 9852
Year:   1991
Reference type:   Journal article
Squib:   1991RYT/WEI9841-9852

Associated entries:

Search Results

Rate expression: k(T) = A (T/298 K)ⁿ e^-Ea/RT
Rate expression units:
First order: s^-1
Second order: cm³/molecule s
Third order: cm⁶/molecule² s
R = 8.314472 J / mole K

Energy Units	J	Molecular Units	Molecule
Pressure Units	bar	Temperature Units	K
Base Volume Unit	cm	Reference Temperature	298.0
Evaluation Temperature	298.0

Use the Plot checkboxes to select data for plotting. Plot selected data using the "Create Plot" button. Click the squib to see extra information about a particular rate constant. Additional help is available.

| |

Squib	Reaction	Temp [K]	A	Order
1991RYT/WEI9841-9852	CO + Fe₂(CO)8 → Fe₂(CO)9	295	7.80E-15	2
1991RYT/WEI9841-9852	Fe(CO)5 + Fe(CO)4 → Fe₂(CO)9	295	5.20E-13	2
1991RYT/WEI9841-9852	Fe(CO)5 + Fe(CO)3 → Fe₂(CO)8	295	2.91E-10	2
1991RYT/WEI9841-9852	Fe(CO)5 + Fe(CO) → Adduct	295	8.60E-11	2
1991RYT/WEI9841-9852	Fe(CO)5 + Fe(CO)2 → Adduct	295	3.70E-10	2

Search returned 5 records.