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Title: Reaction kinetics of coordinatively unsaturated iron carbonyls formed on gas-phase excimer laser photolysis of Fe(CO)5
Journal: J. Phys. Chem.
Volume: 95
Page(s): 9841 - 9852
Year: 1991
Reference type: Journal article
Squib: 1991RYT/WEI9841-9852
Reaction:
Fe(CO)5 + Fe(CO)4 → Fe2(CO)9
Reaction order:
2
Temperature:
295
K
Pressure: 1.33E-2 - 0.11 bar
Rate expression:
5.2x10-13 [±1.51x10-13 cm3/molecule s]
Bath gas:
Ar
Category: Experiment
Data type:
Absolute value measured directly
Excitation technique:
Flash photolysis (laser or conventional)
Analytical technique:
IR absorption
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