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Accessibility information
Author(s):   Sidhu, S.S.; Kiefer, J.H.; Lifshitz, A.; Tamburu, C.; Walker, J.A.; Tsang, W.
Title:   Rate of the retro-diels-alder dissociation of 1,2,3,6-tetrahydropyridine over a wide temperature range
Journal:   Int. J. Chem. Kinet.
Volume:   23
Page(s):   215 - 227
Year:   1991
Reference type:   Journal article
Squib:   1991SID/KIE215-227

Reaction:   1,2,3,6-Tetrahydropyridine1,3-Butadiene + CH2=NH
Reaction order:   1
Temperature:   1000 - 1450 K
Pressure:  1.01 bar
Rate expression:   2.0x1015 [s-1] e-235300 [J/mole]/RT
Bath gas:   He
Category:  Experiment
Data type:   Absolute value measured directly
Excitation technique:   Thermal
Analytical technique:   Laser schlieren

View full bibliographic record.


Rate constant values calculated from the Arrhenius expression:

T (K)k(T) [s-1]
1000 1.02E3
1025 2.04E3
1050 3.94E3
1075 7.38E3
1100 1.34E4
1125 2.38E4
1150 4.11E4
1175 6.93E4
1200 1.15E5
1225 1.85E5
1250 2.94E5
1275 4.59E5
1300 7.03E5
1325 1.06E6
1350 1.57E6
1375 2.30E6
1400 3.33E6
1425 4.74E6
1450 6.68E6